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Cation exchange capacity (CEC)
CEC:
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Is defined as the sum total of the exchangeable cations that a
soil can absorb at a specific pH.
Expression:
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Is expressed as the number of moles of positive charge adsorbed
per unit mass.
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Mostly: centimoles of charge per kilogram of soil
(cmolc/kg).
Example:
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CEC of 15 cmolc/kg: 1 kg soil can hold
15 cmolc of H+ ions and can
exchange this number of charges from H+ ions for the
same number of charges from any other cation [emphasis: exchange reactions take
place on a charge-for-charge basis and not an ion-for ion-basis].
Chemical expression
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The CEC commonly varies from 0.03 and 0.5 mole of positive
charge (molc) per kilogram of soil.
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To express the CEC in whole numbers, the charge is usually
indicated in centimoles per kilogram (cmolc/kg): (100
cmol make up 1 mole. The range of CEC of soils is 3 to 50
cmolc/kg)
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